[Ni(DOTA)] 的合成及其光催化产氢的应用
摘要
本文报道了一种基于镍配合物 ([NiII(DOTA)]) 与 CdS 纳米棒 (1D NWs) 协同作用的光催化水分解体系，并对其进行系统的
光催化析氢实验，优化其工作条件，以期达到最佳的催化效果。实验结果表明，该体系在可见光 (λ=469 nm) 下，体系展
现出优越的产氢性能 (10 h 的产氢量为 252.037
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|参考
[1] Wang Yilin.Controllable preparation and performance
study of Ni-based photocatalyst[D]. Qingdao University of Science
and Technology,2023.DOI:10.27264/d.cnki.gqdhc.2023.000797.
[2] 员晓刚 . 氧化亚铜在光催化水分解中的性能及失活
机理研究 [D]. 天津大学 ,2017.
[3] Yang Qiguang. Biomass energy and its development and
utilisation[J]. Anhui Science and Technology,2005,(12):18-20.
[4] Wang X.Preparation of transition metal-based
electrocatalyst and its performance of hydrogen production by
electrolysis of water[D]. Tianjin University,2018.DOI:10.27356/
d.cnki.gtjdu.2018.002036.
[5] 敖翔 .Fe-N-C 基氧还原反应电催化剂的设计、优化
及其性能研究 [D]. 华中科技大学 ,2021.DOI:10.27157/d.cnki.
ghzku.2021.000284.
[6] Yang H. Synthesis and catalytic hydrogen precipitation
properties of nickel, cobalt, copper and palladium complexes[D].
South China University of Technology,2022.DOI:10.27151/d.cnki.
ghnlu.2022.004477.
[7] WANG Guangqi,BI Yiyang,WANG Jiabo,et al.
Construction of non-precious metal ternary composite
Ni(PO_3)_2-Ni_2P/CdS NPs heterojunctions and visible-light
efficient catalytic hydrogen production[J].Journal of Higher
Education Chemistry,2022,43(06):237-247.
[8] ZHANG Yaqi. Preparation of bimetallic transition metal
phosphides based on bimetallic transition metal phosphides
and their hydrogen precipitation activity[D].Hefei University of
Technology,2021.
[9] Fujishima A, Honda K. Electrochemical photolysis of
water at a semiconductor electrode[J]. nature, 1972, 238(5358):
37-38.
[10] Zhang, J., Liu, B., Li, Y., Zhou, Z., & Zhang, X. (2010).
“Photocatalytic activity of ZnIn2S4 for water splitting under
visible light irradiation.” Journal of Physical Chemistry C,
114(17), 7570-7575.
[11] ZHENG Hui-Qin,FAN Yao-Ting. Visible light-driven
catalytic decomposition of aquatic hydrogen by [FeFe] hydrogenase
mimics[J].Journal of Xinyang Normal College (Natural Science
Edition),2023,36(04):544-549.
[12] CAO Mangan,LIU Yang,ZHANG Shangxi,WANG
Zhenxi,XU Sheng. Synthesis and photocatalytic hydrogen
production properties of chitosan cobalt complexes[J]. Journal of
Higher Education Chemistry,2020,41(04):735-741.
[13] Fujishima, A., & Honda, K. (1972). “Electrochemical
photolysis of water at a semiconductor electrode.” Nature,
238(5358), 37-38.
[14] Zhan Shuzhong,Yang Hao. Design of a novel
photocatalytic hydrogen production system [J]. Laboratory
Research and Exploration, 2021, 40 (07): 6-9.
[15] YU Chuan-Ming,ZENG Sheng-Wei,JIANG Jin-E,et al.
Progress in visible photocatalysis of copper-based compounds[J].
Chemical Progress,2020,39(06):2411-2421.
[ 1 6 ] Z H A N G J i - H o n g , Z H O N G D i - C h a n g , R U
Tong-Bu. Cobalt(II)-based molecular complexes for
photocatalytic carbon dioxide reduction[J]. Journal of Physical
Chemistry,2021,37(05):111-125. [17] Zhang, H., Wang, Q., Zhang,
W., Liu, Y., & Zhang, X. (2018). “Nickel sulfide nanoparticles
loaded on cadmium sulfide as an efficient photocatalyst for
hydrogen production under simulated solar light irradiation.”
Applied Catalysis B: Environmental, 225, 607-615.
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